A new chiral coordination polymer based on [Fe(CN)(6)](4-), Cu2+ cations, and (2S, 3S)-1,2,3,4-tetraaminobutane: synthesis, structure, and ESR spectra

作者：Mironov Yu V^*; Nadolinny V A; Naumov D Yu; Hegetschweiler K; Fedorov V E

来源：Russian Chemical Bulletin, 2007, 56(3): 452-455.

DOI：10.1007/s11172-007-0073-5

• potassium hexacyanoferrate
• chiral coordination polymers
• polydentate amines
• crystal structure

The new chiral coordination polymer [{Cu(NH3)(threo-tab)}(2)Fe(CN)(6)]center dot 8H(2)O was synthesized by the reaction of an aqueous solution of potassium hexacyanoferrate with an ammonia solution of copper(II) chloride and (2S,3S)-1,2,3,4-tetraaminobutane (threo-tab). The structure of the coordination polymer was established by X-ray diffraction. The ESR spectra of this compound were measured for a powder and a single crystal.

• 出版日期2007-3