A facile approach for the synthesis of uniform hollow carbon nanospheres

作者：Li Guangda; Guo Chunli; Sun Changhui; Ju Zhicheng; Yang Lishan; Xu Liqiang^*; Qian Yitai

来源：Journal of Physical Chemistry C, 2008, 112(6): 1896-1900.

DOI：10.1021/jp076189j

Hollow carbon nanospheres (abbreviated as "HCSs") with a yield of about 90% under transmission electron microscope and scanning electron microscopy observations have been synthesized through a facile approach using acetone and sodium azide as reactants at 400 degrees C in a sealed autoclave. These HCSs have an outer diameter of 100-500 nm and a shell thickness of similar to 20 nm. Their total surface area values evaluated from the analyzes of N-2 adsorption isotherm data was 13.1 m(2)/g. The effects of reaction temperature, the dosage of the reagent, and the capacity of autoclave on the formation of the final products have been studied. Through tuning the experimental parameters, olivary carbon particles or carbon rods also have been selectively prepared. In addition, when acetone was replaced by polyethylene glycol or glucose, HCSs were obtained at 400 degrees C with a yield of similar to 90 and similar to 30%, respectively. On the basis of the. experimental results, a possible formation mechanism of the hollow carbon nanospheres was discussed.

• 出版日期2008-2-14
• 单位山东大学