Highly selective direct reductive amidation of nitroarenes with carboxylic acids using cobalt(II) phthalocyanine/PMHS

作者:Kumar Vishal; Kumar Manoranjan; Sharma Sushila; Kumar Neeraj*
来源:RSC Advances, 2014, 4(23): 11826-11830.
DOI:10.1039/c3ra46619a

摘要

Cobalt phthalocyanine has been employed for highly chemoselective direct reductive amidation of nitroarenes with non-activated carboxylic acids using polymethylhydrosiloxane as an inexpensive, stable and environmentally benign reducing agent. A large range of functional groups such as amide, ester, nitrile, halogen, lactone, hydroxy, alkene and heterocycles were well tolerated.

  • 出版日期2014