An unprecedented 2D isopolymolybdate with (3(2)center dot 4)(3(2)center dot 5(3)center dot 8)(3 center dot 4(2)center dot 5(4)center dot 6 center dot 8(2))(3(4)center dot 4(3)center dot 5(4)center dot 6(4)) topology

作者：Sha Jingquan; Wang Cheng; Peng Jun^*; Tian Aixiang; Chen Jing; Zhang Pengpeng

来源：Inorganic Chemistry Communications, 2007, 10(12): 1469-1472.

DOI：10.1016/j.inoche.2007.09.011

• isopolymolybdate
• hydrothermall synthesis
• topology
• electrochemical property

A novel two-dimensional molybdenum oxide polymer, [Mo4O13](n) center dot 2nH(3)O, has been prepared under specific hydrothermal conditions and characterized by IR spectroscopy and TG analysis. Single-crystal X-ray diffraction analysis reveals that compound 1 exhibits a (3, 4, 5, 6)-connected 2D layer structure with (3(2)center dot 4)(3(2)center dot 5(3)center dot 8)(3 center dot 4(2)center dot 5(4)center dot 6 center dot 8(2))( 3(4)center dot 4(3)center dot 5(4)center dot 6(4)) topology, which is constructed by two parallel molybdenum oxide dimeric chains (Mo2O10)(n) bound together by the dimer of Mo2O9 subunits via the sharing of corners. Additionally, the electrochemistry activity of compound 1 is also reported.

• 出版日期2007-12
• 单位东北师范大学; 佳木斯大学; 黑龙江大学