Nickel-Catalyzed Reductive Etherification of Aldehydes at Room Temperature: C-O vs C-C Bond Formation

作者：Rahimi Sajjad; Panahi Farhad^*; Bahmani Marzieh; Iranpoor Nasser^*

来源：Journal of Organic Chemistry, 2018, 83(2): 973-979.

DOI：10.1021/acs.joc.7b02281

The reaction of secondary and tertiary benzyl alcohols activated by 2,4,6-trichloro-1,3,5-triazine (TCT) with aldehydes in the presence of NiCl2-dmg as a precatalyst in ethylene glycol afforded ethers at room temperature. A selective C-O vs C-C bond formation was observed for the secondary and tertiary benzyl alcohols in comparison with primary ones.

• 出版日期2018-1-19