Highly Selective Sensing of CO, C6H6, and C7H8 Gases by Catalytic Functionalization with Metal Nanoparticles

作者：Kim Jae Hun; Wu Ping^*; Kim Hyoun Woo^*; Kim Sang Sub^*

来源：ACS Applied Materials & Interfaces, 2016, 8(11): 7173-7183.

DOI：10.1021/acsami.6b01116

• selective sensing gas
• metal functionalization
• catalyst
• d-band
• theory

We have fabricated multiple networked SnO2 nanowires and subsequently decorated-them with uniformly distributed metal nanoparticles (NPs). The sensing tests indicated that the Pt-, Pd-, and Au-decorated SnO2 nanowires exhibited excellent sensing behavior, specifically for C7H8, C6H6, and CO gases, respectively. We discussed the associated sensing mechanisms in regard to the selective catalytic effects of metal NPs. In addition, by means of d-band theory, we explained the catalytic capabilities of each metal and proposed design principles for exploring new catalytic metals. The present study will pave the way for further development of high-selectivity sensors.

• 出版日期2016-3-23