A new designed hydrazine group-containing ruthenium complex used for catalytic hydrogenation of esters

作者：Tan, Xuefeng; Wang, Qingli; Liu, Yuanhua; Wang, Fangyuan; Lv, Hui^*; Zhang, Xumu

来源：Chemical communications, 2015, 51(61): 12193-12196.

DOI：10.1039/c5cc04242a

• CARBOXYLIC-ACID ESTERS
• ASYMMETRIC HYDROGENATION
• SELECTIVE HYDROGENATION
• EFFICIENT HYDROGENATION
• BIFUNCTIONAL ADDITION
• CHIRAL ALCOHOLS
• REDUCTION
• MECHANISM
• KETONES
• LIGANDS

A hydrazine group-containing nitrogen-phosphine ligand and corresponding ruthenium complexes were synthesized. When these complexes were used for hydrogenation of esters, excellent performance was observed (TON up to 17 200). A wide substrate scope was suitable for this catalytic system.

• 出版日期2015
• 单位武汉大学