Azulene based metal-organic frameworks for strong adsorption of H-2

作者:Barman Samir; Furukawa Hiroyasu*; Blacque Olivier; Venkatesan Koushik; Yaghi Omar M; Berke Heinz
来源:Chemical Communications, 2010, 46(42): 7981-7983.
DOI:10.1039/c0cc02589e

摘要

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.

  • 出版日期2010