科研之友
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摘要
A novel organic-inorganic molybdenum arsenate compound with chain structure, [As(phen)](2)[As2Mo2O14] (phen = 1,10'-phenanthroline) 1, has been synthesized by the hydrothermal reaction and structurally characterized. Compound 1 represents the first example which contains an unusual 1D (As/Mo/O) chain with the phen ligands directly coordinated to the As atoms. Furthermore, a two-dimensional supra-molecule layer is formed by pi-pi stacking interactions of the phen groups between adjacent chains. The electrochemical behavior of 1 modified CPE (1-CPE) has been also studied.
