摘要

The reactions of Cd(NO3)(2)center dot 4H(2)O, Co(NO3)(2)center dot 6H(2)O with nicotinic add and 1,2-Di(4-pyridyl) ethylene under hydrothermal reaction conditions resulted in a metal-organic polymer [(H2O)Cd(C6H4O2N)(2)](2)[(C6H4O2N)(2)Co(H2O)(2)] 1. The compound 1 is the first nicotinato-linked mixed cobalt-cadmium compound displaying a square basketlike thick covalent 2-D layer structure.

  • 出版日期2014-12

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