Utilization of acetone-butanol-ethanol-water mixture obtained from biomass fermentation as renewable feedstock for hydrogen production via steam reforming: Thermodynamic and energy analyses

作者：Kumar Brajesh; Kumar Shashi^*; Sinha Shishir; Kumar Surendra^*

来源：Bioresource Technology, 2018, 261: 385-393.

DOI：10.1016/j.biortech.2018.04.035

• Hydrogen
• Steam reforming
• Energy
• Exergy
• Acetone-butanol-ethanol-water mixture

A thermodynamic equilibrium analysis on steam reforming process to utilize acetone-butanol-ethanol-water mixture obtained from biomass fermentation as biorenewable fuel has been performed to produce clean energy carrier H-2 via non-stoichiometric approach namely Gibbs free energy minimization method. The effect of process variables such as temperature (573-1473 K), pressure (1-10 atm), and steam/fuel molar feed ratio (F-ABE = 5.5-12) have been investigated on equilibrium compositions of products, H-2, CO, CO2, CH4 and solid carbon. The best suitable conditions for maximization of desired product H2, suppression of CH4, and inhibition of solid carbon are 973 K, 1 atm, steam/fuel molar feed ratio = 12. Under these conditions, the maximum molar production of hydrogen is 8.35 with negligible formation of carbon and methane. Furthermore, the energy requirement per mol of H-2 (48.96 kJ), thermal efficiency (69.13%), exergy efficiency (55.09%), exergy destruction (85.36 kJ/mol), and generated entropy (0.29 kJ/mol.K) have been achieved at same operating conditions.

• 出版日期2018-8