Ambipolar Low-bandgap Copolymers Consisting of Dithienoketopyrrole for All-Polymer Solar Cells

作者：Ide Marina^*; Koizumi Yoshiko; Saeki Akinori; Seki Shu

来源：Journal of Photopolymer Science and Technology, 2013, 26(2): 217-221.

• bulk heterojunction
• organic photovoltaics
• low-bandgap polymer
• microwave conductivity

The new low-band gap copolymers containing electron-accepting thienoisoindigo (TIDG) exhibit the low-lying lowest unoccupied molecular orbital (LUMO) at -3.8 eV. This envisions their use as n-type polymer in combination with typical p-type regioregular poly(3-hexylthiophene) (P3HT) towards all-polymer organic photovoltaics (OPV). The alternating fluorene and TIDG copolymer, PFTIDG, shows the electronic absorption maximum at 744 nm in the film states, of which spectrum is complementary to that of P3HT and thus advantageous for covering the wide solar spectrum. The laser and Xe-flash time-resolved microwave conductivity (TRMC) evaluations were performed for screening the effects of p/n blend ratio and thermal annealing in bulk heterojunction framework. The power conversion efficiency of 0.06% was obtained for pre-annealed P3HT:PFTIDG = 1:1 together with a high open circuit voltage of 0.92 V, which is suggestive of ambipolar characteristics of PFTIDG.

• 出版日期2013