A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property

作者：Tai Xi Shi^*; You Hai Ying

来源：Crystals, 2015, 5(4): 608-616.

DOI：10.3390/cryst5040608

• N-acetyl-L-phenylalanine
• Zn(II) coordination polymer
• 1D chained structure
• antitumor activity
• luminescent property

A new 1D chained coordination polymer of Zn(II), {[Zn(L)(2)(4,4-bipy)](H2O)}(n)(1) (HL = N-acetyl-l-phenylalanine; 4,4-bipy = 4,4-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. Theresults show that each asymmetric unit of Zn(II) complex belongs to monoclinic, space group P2(1) with a = 11.421(2) angstrom, b = 9.2213(17) angstrom, c = 15.188(3) angstrom, beta = 106.112(3)degrees, V = 1536.7(5) angstrom(3), Z = 2, Dc = 1.444 g.cm(-3), mu = 0.857 mm(-1), F(000) = 696, and final R-1 = 0.0439, omega R-2 = 0.1013. The molecules form one-dimensional chained structure by its the bridging 4,4-bipyridine ligands. The antitumor activities and luminescent properties of Zn(II) coordination polymer have also been investigated.

• 出版日期2015-12
• 单位潍坊学院