Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)(2)SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)(2), OtBu)

作者：Azhakar Ramachandran; Ghadwal Rajendra S^*; Roesky Herbert W; Wolf Hilke; Stalke Dietmar

来源：Organometallics, 2012, 31(12): 4588-4592.

DOI：10.1021/om3003762

Reactions of silylenes with organic substrates generally lead to silicon(IV) compounds. Ligand substitution at the silicon(II) atom of silylene, without changing the formal +2 oxidation state, is very rare. We report herein a straightforward route to functionalized silylenes LSiX (L = PhC(NtBu)(2) and X = PPh2 (1), NPh2 (2), NCy2(3), NiPr2 (4), NMe2 (5), N(SiMe3)(2) (6), OtBu (7)). Silylenes 1-7 have been prepared in quantitative yield by a modified ligand exchange reaction of PhC(NtBu)(2)SiCl (LSiCl) with the corresponding lithium or potassium salts. Compounds 1-7 were characterized by spectroscopic and spectrometric techniques. Single-crystal X-ray structures of 1, 3, and 4 were determined.

• 出版日期2012-6-25