Advanced microwave-assisted production of hybrid electrodes for energy applications

作者：Sherrell, Peter C.^*; Chen, Jun; Razal, Joselito M.; Nevirkovets, Ivan P.; Crean, Carol; Wallace, Gordon G.; Minett, Andrew I.

来源：Energy & Environmental Science, 2010, 3(12): 1979-1984.

DOI：10.1039/c0ee00352b

• CARBON NANOTUBE ELECTRODES
• ELECTROCHEMICAL CAPACITORS
• FUEL-CELLS
• NANOPARTICLES
• CATALYSTS
• PERFORMANCE
• METAL
• PD

Carbon nanotubes are one of the most prominent materials in research for creating electrodes for portable electronics. When coupled with metallic nanoparticles the performance of carbon nanotube electrodes can be dramatically improved. Microwave reduction is an extremely rapid method for producing carbon nanotube-metallic nanoparticle composites, however, this technique has so far been limited to carbon nanotube soot. An understanding of the microwave process and the interactions of metallic nanoparticles with carbon nanotubes have allowed us to extend this promising functionalisation route to pre-formed CNT electrode architectures. Nanoparticle reduction onto preformed architectures reduces metallic nanoparticle waste as particles are not formed where there is insufficient porosity for electrochemical processes. A two-fold increase in capacitive response, stable over 500 cycles, was observed for these composites, with a maximum capacitance of 300 F g(-1) observed for a carbon Nanoweb electrode.

• 出版日期2010-12