The effect of Ni content on a highly active Ni-Al2O3 catalyst prepared by the homogeneous precipitation method

作者：Seo Yong Seg^*; Jung You Shick; Yoon Wang Lai; Jang In Gab; Lee Tae Won

来源：International Journal of Hydrogen Energy, 2011, 36(1): 94-102.

DOI：10.1016/j.ijhydene.2010.09.082

• Ni-Al2O3
• Ni content
• Homogeneous precipitation
• Molten carbonate fuel cell (MCFC)
• Internal reforming

Highly active Ni-Al2O3 catalysts were prepared by the homogeneous precipitation method with a variety of high nickel contents ranging from 30 to 70 wt.%. The effects of nickel content on the physicochemical properties and catalytic activities of the Ni-Al2O3 catalysts were investigated. XRD measurements showed that the catalyst with 30 Ni wt.% only had a diffraction peak corresponding to NiAl2O4, whereas the catalysts of 50, 60 and 70 Ni wt.% had diffraction peaks corresponding to NiO and NiAl2O4. Hydrogen chemisorption results showed that the nickel surface area increased with increasing nickel content in the order: 30 < 40 < 50 < 60 < 70 Ni wt.%. Specifically, the nickel surface area increased steadily from 11 to 22 m(2)/g with increasing the nickel content from 30 to 50 wt.%, after which it stayed nearly constant at 22 m(2)/g despite the increase in nickel content from 50 to 70 wt.%. TEM images of the reduced Ni-Al2O3 catalysts revealed that the average sizes of the Ni particles were 12, 13 and 16 nm for the catalysts with 30, 50 and 70 Ni wt.%, respectively, suggesting that a higher nickel content yielded a larger Ni particle. The catalytic performance of methane steam reforming showed that the catalytic reaction rate increased steadily with increasing nickel content from 30 to 50 wt.%, after which it stayed nearly constant despite that the nickel content increased to over 50 wt.%. As a result, about 50 wt.% of nickel was found to be a reasonable nickel content to obtain the maximum catalytic activity.

• 出版日期2011-1