A new bitrack sinusoid-like chain templated by Wells-Dawson type polyoxometalate

作者：Wang Xiuli^*; Hu Hailiang; Tian Aixiang; Lin Hongyan; Li Jin; Shi Limin

来源：Inorganic Chemistry Communications, 2010, 13(6): 745-748.

DOI：10.1016/j.inoche.2010.03.037

• Wells-Dawson Polyoxometalate
• Inorganic-organic hybrids
• Template synthesis
• Electrochemical property

A new Wells-Dawson type polyoxometalate (POM)-templated compound, [Cu(4)(mu(2)-O)(2)(4,4'-bpo)(4)(INA)(2)(H(2)O)(4)][(P(2)W(18)O(62))]center dot H(2)O (1) (4,4'-bpo = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole; INA = pyridine-4-carboxylic acid), has been hydrothermally synthesized. Compound 1 contains a novel bitrack sinusoid-like chain constructed from alternating dicopper units and non-linear rigid 4,4'-bpo linkers. Induced by POM templates, the adjacent chains formed elliptical spaces to accommodate the Wells-Dawson type anions.

• 出版日期2010-6
• 单位渤海大学