In-Situ Catalytic Pyrolysis of Dealkaline Lignin Over MMZ-H beta

作者:Kim Young Min; Park Rae su; Lee Eun Hwa; Jeon Jong Ki; Kim Sang Chai; Jung Sang Chul; Kim Seungdo; Park Young Kwon*
来源:Journal of Nanoscience and Nanotechnology, 2017, 17(4): 2760-2763.
DOI:10.1166/jnn.2017.13347

摘要

In-situ catalytic pyrolysis of dealkaline lignin (DL) over MMZ-H beta was performed using a pyrolyzergas chromatography/mass spectroscopy for the first time. Non-catalytic pyrolysis of DL mainly produced large amounts of phenolics such as mono-phenol, alkylphenols, guaiacols, eugenols, and vanillin. By applying MMZ-H beta, the amounts of these phenolics were dramatically decreased with the increase of aromatics such as benzene, toluene, ethylbenzene, xylenes, and naphthalenes. The higher conversion efficiency from phenolics to aromatics was obtained by increasing the catalyst to DL ratio from 1/1 to 5/1.

  • 出版日期2017-4