Assessing the potential of group 13 and 14 metal/metalloid phthalocyanines as hole transport layers in organic light emitting diodes

作者：Plint Trevor; Lessard Benoit H; Bender Timothy P

来源：Journal of Applied Physics, 2016, 119(14): 145502.

DOI：10.1063/1.4945377

In this study, we have assessed the potential application of group 13 and 14 metal and metalloid phthalocyanines ((X)(n)-MPcs) and their axially substituted derivatives as hole-transporting layers in organic light emitting diodes (OLEDs). OLEDs studied herein have the generic structure of glass/ITO/(N,N'-di(1-naphthyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine (NPB) or (X)(n)-MPc)(50 nm)/Alq(3) (60 nm)/LiF (1 nm)/Al (80 nm), where X is an axial substituent group. OLEDs using chloro aluminum phthalocyanine (Cl-AlPc) showed good peak luminance values of 2620 +/- 113 cd/m(2) at 11 V. To our knowledge, Cl-AlPc has not previously been shown to work as a hole transport material (HTL) in OLEDs. Conversely, the di-chlorides of silicon, germanium, and tin phthalocyanine (Cl-2-SiPc, Cl-2-GePc, and Cl-2-SnPc, respectively) showed poor performance compared to Cl-AlPc, having peak luminances of only 3864 cd/m(2) (12 V), 2361 cd/m(2) (8.5 V), and 5965 cd/m(2) (13.5 V), respectively. However, by performing a simple axial substitution of the chloride groups of Cl-2-SiPc with pentafluorophenoxy groups, the resulting bis(pentafluorophenoxy) silicon phthalocyanine (F-10-SiPc) containing OLED had a peak luminance of 5141 +/- 941 cd/m(2) (10 V), a two order of magnitude increase over its chlorinated precursor. This material showed OLED characteristics approaching those of a baseline OLED based on the well-studied triarylamine NPB. Attempts to attach the pentafluorophenoxy axial group to both SnPc and GePc were hindered by synthetic difficulties and low thermal stability, respectively. In light of the performance improvements observed by simple axial substitution of SiPc in OLEDs, the use of axially substituted MPcs in organic electronic devices remains of continuing interest to us and potentially the field in general.

• 出版日期2016-4-14