A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2]center dot 12H(2)O (L-tart = L-tartrate)

作者：Craig Gavin A; Woodall Christopher H; McKellar Scott C; Probert Michael R; Kamenev Konstantin V; Moggach Stephen A; Brechin Euan K; Parsons Simon^*; Murrie Mark

来源：Dalton Transactions, 2015, 44(42): 18324-18328.

DOI：10.1039/c5dt03320a

The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

• 出版日期2015