NH2-MIL-53(Al): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

作者：Serra Crespo Pablo; van der Veen Monique A; Gobechiya Elena; Houthoofd Kristof; Filinchuk Yaroslav; Kirschhock Christine E A; Martens Johan A; Sels Bert F; De Vos Dirk E^*; Kapteijn Freek; Gascon Jorge

来源：Journal of the American Chemical Society, 2012, 134(20): 8314-8317.

DOI：10.1021/ja300655f

The metal organic framework NH2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

• 出版日期2012-5-23