An unprecedented 1-D mixed-valence Cu(II)/Cu(I) metal-organic framework bearing 2-phenyl imidazole dicarboxylates

作者：Zhu Yu; Wang Wen yue; Guo Meng wei; Li Gang^*; Lu Hui jie

来源：Inorganic Chemistry Communications, 2011, 14(9): 1432-1435.

DOI：10.1016/j.inoche.2011.05.039

• Mixed-valence
• Copper
• Polymer
• Phenyl imidazole dicarboxylate
• Crystal structure

An unprecedented mixed-valence Cu(I)/Cu(II) metal-organic framework {[Cu(2)(HPhIDC)(OH)]center dot H(2)O}(n) (H(3)PhIDC=2-phenyl-1H-imidazole-4,5-dicarboxylic acid) (1) has been solvothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, XPS spectrum and single crystal X-ray diffraction analysis. In 1, each Cu(I) ion is two-coordinated by imidazole and OH(-)units. The HPhIDC(2-)ligands connect Cu(II) ions leading to a one-dimensional chain structure. The thermal properties of 1 are reported.

• 出版日期2011-9
• 单位郑州大学