Facile Synthesis and Lateral pi-Expansion of Bisanthenes

作者:Konishi Akihito; Hirao Yasukazu; Matsumoto Kouzou; Kurata Hiroyuki; Kubo Takashi*
来源:Chemistry Letters, 2013, 42(6): 592-594.
DOI:10.1246/cl.130153

摘要

The improved Scholl reaction allows for the direct cyclization of anthracene oligomers to give bisanthene, teranthene, and quateranthene. Furthermore, a variety of pi-expanded bisanthenes are obtained by the Diels-Alder cycloaddition of bisanthene with several arynes. These reactions would allow us to synthesize various size- and shape-controlled polyperiacenes.

  • 出版日期2013-6-5