科研之友
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摘要
Aqueous sodium-ion batteries (SIBs) represent a class of green electrochemical technology for large-scale storage of sustainable energies such as wind power and solar radiation, owing to their low cost, environmental friendliness, and reliable safety. However, there is still lack of available anode materials for aqueous SIBs. Herein, nanocrystal-assembled porous Na3MgTi(PO4)(3) aggregates are reported as novel anode material for aqueous SIBs. The crystal structure, morphological features, and electrochemical properties have been analyzed with X-ray diffraction, scanning electron microscopy, transition electron microscopy, cyclic voltammetry, and charge/discharge measurements. As revealed, the material possesses a porous nanostructure composed of 5nm nanocrystals and mesoporous channels. During Na-insertion/extraction, it undergoes a one-step single-phase reaction mechanism through reversible electrochemistry of the Ti4+/Ti3+ redox couple, showing a rechargeable capacity of 54mAhg(-1) and an average working potential of -0.63V (vs. Ag/AgCl) at 0.2C. More importantly, good rate capacity (33mAhg(-1) at 4C) and excellent cycling performance (94.2% capacity retention after 100cycles at 0.5C) are achieved due to the unique porous nanostructure and robust compositional framework. The finding in this work would create new opportunities for design of low-cost, long-cycling aqueous SIBs.
- 出版日期2017-9-18
- 单位东北林业大学
