Mechanistic aspects of the gas-phase coupling of thioanisole and chlorobenzene to dibenzothiophene catalyzed by atomic Ho+

作者:Zhou Shaodong; Schlangen Maria; Schwarz Helmut*
来源:Physical Chemistry Chemical Physics, 2015, 17(14): 9564-9568.
DOI:10.1039/c5cp01038a

摘要

Mechanistic aspects of the novel gas-phase generation of dibenzothiophene via coupling of thioanisole and chlorobenzene, employing atomic Ho+ as a catalyst, have been investigated using Fourier-transform ion cyclotron resonance mass spectrometry in conjunction with density functional theory (DFT) calculations.

  • 出版日期2015