Coordination and organometallic compounds as precursors of classic and less-common nanostructures: recent advances

作者：Kharisov Boris I; Kharissova Oxana V^*; Mendez Ubaldo Ortiz

来源：Journal of Coordination Chemistry, 2013, 66(21): 3791-3828.

DOI：10.1080/00958972.2013.851382

• Nanostructures
• Coordination compounds
• Organometallics
• Pyrolysis
• Decomposition

The synthesis of various classic and less-common inorganic nanostructures (nanoparticles, microflowers, nanourchins, nanofilms, nanorods, nanoleaves, nanowires, etc.) consisting mainly of elemental metals, intermetallics, oxides and sulfides from metal complexes as precursors is reviewed. To prepare nanoparticles/nanostructures, a series of complexes of N-, O-, S-, N, O-, N, S(Se)-, and N, P-containing ligands, as well as sigma- and -organometallic compounds of mainly transition metals have been treated using pyrolysis, laser, ultrasonic irradiation, CVD techniques, electron beam irradiation, and related sophisticated techniques from 100 to 700 degrees C. The obtained nanoparticles possess a series of useful applications, in particular as catalysts, sensors, sorbents, and remediation agents.

• 出版日期2013-11-10