Novel Urchin-like CuO Synthesized by a Facile Reflux Method with Efficient Olefin Epoxidation Catalytic Performance

作者：Xu Linping; Sithambaram Shanthakumar; Zhang Yashan; Chen Chun Hu; Jin Lei; Joesten Raymond; Suib Steven L^*

来源：Chemistry of Materials, 2009, 21(7): 1253-1259.

DOI：10.1021/cm802915m

CuO is an important transition metal oxide with a narrow bandgap (E(g) = 1.2 eV). CuO has been used as a catalyst, a gas sensor, in anode materials for Li ion batteries. CuO has also been used to prepare high temperature superconductors and magnetoresi stance materials. In this paper, CuO with urchin-like morphologies has been synthesized via a simple reflux method. The reflux method has advantages over other solution-based techniques, such as ease of operation, safety, and high yield (95%). XRD results showed pure tenorite CuO was produced. FE-SEM exhibited an urchin-like morphology of CuO, which is composed of aggregates of nanosized strips. HR-TEM showed that the strips were single crystals with the lattice fringe of 2.3 angstrom, which corresponds to (111). DSC and TGA results suggested that as-synthesized CuO had high thermal stability. Time-dependent experiments were conducted to illustrate the evolution of the urchin-like morphology and crystal phase formation of CuO. The effects of copper sources and precipitators on the phase and morphology of the products were studied. As-synthesized CuO showed much better catalytic performance, increased yield (from 64.3% to 89.5%) for olefin epoxidation than commercial CuO and CuO prepared by thermal decomposition of copper hydroxide.

• 出版日期2009-4-14