Novel MEMS-Based Gas-Cell/Heating Specimen Holder Provides Advanced Imaging Capabilities for In Situ Reaction Studies

作者：Allard Lawrence F^*; Overbury Steven H; Bigelow Wilbur C; Katz Michael B; Nackashi David P; Damiano John

来源：Microscopy and Microanalysis, 2012, 18(4): 656-666.

DOI：10.1017/S1431927612001249

• in situ
• gas reaction
• gas cell
• high-resolution
• electron microscopy
• catalysts
• MEMS

In prior research, specimen holders that employ a novel MEMS-based heating technology (Aduro (TM)) provided by Protochips Inc. (Raleigh, NC, USA) have been shown to permit sub-Angstrom imaging at elevated temperatures up to 1,000 degrees C during in situ heating experiments in modern aberration-corrected electron microscopes. The Aduro heating devices permit precise control of temperature and have the unique feature of providing both heating and cooling rates of 10(6 degrees)C/s. In the present work, we describe the recent development of a new specimen holder that incorporates the Aduro heating device into a "closed-cell" configuration, designed to function within the narrow (2 mm) objective lens pole piece gap of an aberration-corrected JEOL 2200FS STEM/TEM, and capable of exposing specimens to gases at pressures up to 1 atm. We show the early results of tests of this specimen holder demonstrating imaging at elevated temperatures and at pressures up to a full atmosphere, while retaining the atomic resolution performance of the microscope in high-angle annular dark-field and bright-field imaging modes.

• 出版日期2012-8