Asymmetric cyclopropanation in ionic liquids promoted by dicopper complexes of ditopic ligands

作者:Garcia Jose I*; Herrerias Clara I; Lopez Sanchez Beatriz; Mayoral Jose A; Minana Ana C
来源:Tetrahedron: Asymmetry , 2014, 25(10-11): 833-837.
DOI:10.1016/j.tetasy.2014.04.017

摘要

The use of ionic liquid phases to immobilise dicopper complexes of ditopic chiral ligands bearing bis(oxazoline) moieties has been explored in the enantioselective cyclopropanation reaction of styrene with ethyl diazoacetate. The recoverability of these catalytic phases has been studied using different ionic liquids and ligands. The origin of the ionic liquid is determinant both for the catalytic results and the reusability of the system.

  • 出版日期2014-5-31