Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery

作者:Stoeck Ulrich; Senkovska Irena; Bon Volodymyr; Krause Simon; Kaskel Stefan*
来源:Chemical communications, 2015, 51(6): 1046-1049.
DOI:10.1039/c4cc07920e

摘要

Two new mesoporous metal-organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal-organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm(3) g(-1) and a specific BET surface area of 4081 and 6344 m(2) g(-1), respectively, and high gas uptake at room temperature and high pressure.

  • 出版日期2015