Novel Stable Silyl, Germyl, and Stannyl Germanium(II) Compounds Containing an Amidinato Ligand

作者：Matioszek Dimitri; Katir Nadia; Ladeira Sonia; Castel Annie^*

来源：Organometallics, 2011, 30(8): 2230-2235.

DOI：10.1021/om200024d

Reactions of the N,N'-chelated chlorogermanium(II) compound [Me(3)SiNC(Ph)NSiMe(3)]GeCl with the magnesium reagents. Mg[E(Si/Me(3))(3)](2) (E = Si, Ge, Sn) gave the new metallyl germylenes [Me(3)SiNC(Ph)NSiMe(3)]GeE(SiMe(3))(3), representing the first isolated silyl- and stannylgermylenes. These compounds have been fully characterized by multinuclear NMR spectroscopy and their structures determined by X-ray diffraction analysis.

• 出版日期2011-4-25