Unique structural micro-adjustments in a new benzothiadiazole-derived Zn(II) metal organic framework via simple photochemical decarboxylation

作者：Han, Xiao; Cheng, Qing; Meng, Xiangru; Shao, Zhichao; Ma, Ke; Wei, Donghui; Ding, Jie^*; Hou, Hongwei^*

来源：Chemical communications, 2017, 53(74): 10314-10317.

DOI：10.1039/c7cc06125k

• LIGHT-INDUCED DECARBOXYLATION
• 2ND-ORDER NONLINEAR OPTICS
• COORDINATION POLYMERS
• ENERGY-TRANSFER
• ZIRCONIUM MOF
• ACIDS
• PHOTODECARBOXYLATION
• LUMINESCENCE
• MECHANISM
• SORPTION

The first example of micro-adjustments of a metal organic framework (MOF) structure was observed in a new Zn(II) MOF (Zn-BTDCM1) derived from a benzothiadiazole-4,7-dicarboxylic acid (H2BTDC) ligand using a light-driven decarboxylation process. Interestingly, such decarboxylation occurs at the non-chelated wing of the ligand, which induced a change in the capability of the MOF for physical N-2 adsorption and chemical NH3 gas adsorption.

• 出版日期2017-9-21
• 单位郑州大学