Direct assembly synthesis of metal complex-semiconductor hybrid photocatalysts anchored by phosphonate for highly efficient CO2 reduction

作者:Suzuki Tomiko M*; Tanaka Hiromitsu; Morikawa Takeshi; Iwaki Masayo; Sato Shunsuke; Saeki Shu; Inoue Masae; Kajino Tsutomu; Motohiro Tomoyoshi
来源:Chemical communications, 2011, 47(30): 8673-8675.
DOI:10.1039/c1cc12491a

摘要

Hybrid photocatalysts consisting of a ruthenium complex and p-type photoactive N-doped Ta2O5 anchored with an organic group were successfully synthesized by a direct assembly method. The photocatalyst anchored by phosphonate exhibited excellent photoconversion activity of CO2 to formic acid under visible-light irradiation with respect to the reaction rate and stability.

  • 出版日期2011