Lithium - Air Battery: Promise and Challenges

作者：Girishkumar G^*; McCloskey B; Luntz A C; Swanson S; Wilcke W

来源：Journal of Physical Chemistry Letters, 2010, 1(14): 2193-2203.

DOI：10.1021/jz1005384

The lithium-air system captured worldwide attention in 2009 as a possible battery for electric Vehicle propulsion applications. If successfully loped, 7 this battery could provide an energy source for electric vehicles rivaling that of gasoline in terms of usable energy density. However, there are numerous scientific and technical challenges that must be overcome if this alluring promise is to turn into reality. The fundamental battery chemistry during discharge is thought to be the evidence that the oxidation of lithium metal, at the anode and reduction of Oxygen from the.,. With aprotic electrolytes, as used in Li-ion batteries, there is some evidence that the process can be reversed by applying an external Potential, i.e., that such a battery can be electrically recharged. This paper summarizes the authors' view of the promise and challenges facing development of practical Li-air batteries and the current understanding, of its chemistry. However, it Must be appreciated that this' perspective represents only a snapshot in a very rapidly evolving picture.

• 出版日期2010-7-15