An electrochemical mechanisms study on steel/IrO2-Sb2O3 electrodes for oxidation of phenol in water

作者：Jayathilaka Pavithra Bhakthi; Pathiraja Gayani Chathurika; Bandara Athula; Subasinghe Nalaka Deepal; Nanayakkara Nadeeshani^*

来源：Canadian Journal of Chemistry, 2015, 93(5): 536-541.

DOI：10.1139/cjc-2014-0304

• benzoquinone
• catechol
• oxidation mechanisms
• phenol
• steel/IrO2-Sb2O3 anode

Phenol, a known water pollutant, was electrochemically oxidized on a steel/IrO2-Sb2O3 novel anode. Since the oxidation mechanisms vary based on the anode material, a mechanisms study of electrooxidation of phenol on it was conducted. The phenol oxidation was carried out at 20 mA/cm(2) constant current density with a pH 11.00 Na2SO4 medium at room temperature. During 6 h of electrolysis, samples were tested for chemical oxygen demand removal efficiency of the anode. The steel/IrO2-Sb(2)O(3)anode showed 76.3% chemical oxygen demand removal efficiency. Both 4-nitroso-N,N-dimethylaniline and the HCO3-/CO32- radical scavenger tests confirmed the formation and presence of the hydroxyl radicals in the system. Therefore, it was concluded that the hydroxyl radicals that are generated on the anode surface are the main cause for the oxidation mechanism. Moreover, ICE, HPLC, and UV-vis absorbance and cyclic voltammetry results confirmed the presence of catechol and benzoquinone as intermediates and the reaction mechanism.

• 出版日期2015-5