科研之友
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摘要
The first method for the highly enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted olefins has been developed. By employing either of the P-chirogenic phosphine ligands BenzP* and QuinoxP*, linear aldehydes with beta-chirality can be prepared in a highly enantioselective fashion with good chemo- and regioselectivities.
- 出版日期2011-11-30
