Diaquabis[(E)-2-(4-oxopentan-2-ylideneamino)benzoato-kappa O]dipyridinemanganese(II)

作者:Shi Shao Min; Hu Zong Qiu*
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63(2): M426-M428.
DOI:10.1107/S1600536806056212

摘要

The Mn atom in the title compound, [Mn(C12H13NO2)(2)-(C5H5N)(2)(H2O)(2)], is coordinated by two pyridine heterocycles, two water molecules and an O-atom donor in two substituted benzoate groups, in an all-trans arrangement with the Mn atom on a center of inversion. The benzoate mean plane is inclined to the coordination plane formed by the four O atoms, with a dihedral angle of 43.4 (1)degrees. The dihedral angle between the planes of the benzene ring and the Schiff base is 49.5 (1)degrees.