Facile synthesis and optical properties of bithiophenesilane monodendrons and dendrimers

作者:Luponosov Yuriy N; Ponomarenko Sergei A*; Surin Nikolay M; Muzafarov Aziz M
来源:Organic Letters, 2008, 10(13): 2753-2756.
DOI:10.1021/ol800811a

摘要

Three generations of bithiophenesilane monodendrons and dendrimers consisting of 3-45 2,2'-bithiene-5,5'-diyl units were synthesized by means of effective coupling reactions between the corresponding bithienyllithium derivatives and chlorosilanes. These compounds show efficient photoluminescence in the violet-blue region, the quantum yield of which is 5-15 times higher than that for the parent bithiophene or bithiophenesilanes.

  • 出版日期2008-7-3