A Synthetic Study and Characterization of the Pt(II) Complexes with Bipyridines Back-Born System

作者：Jo Woongkyu; Son Seokhwan; Jo Hyeongjun; Kim Byeongcheol; Kwak Cheehun; Jung Sangchul; Lee Jihoon; Ahn Hogeun; Chung Minchul^*

来源：Journal of Nanoscience and Nanotechnology, 2014, 14(8): 6213-6216.

DOI：10.1166/jnn.2014.8310

• Platinum
• Bipyridine
• Photoluminescence
• 5,5 '-Dimethyl-2,2 '-Dipyridyl
• OLED

T he reaction of platinum [Pt(5,5-dmbpy)]Cl-2 (5,5-dmbpy = 5,5'-dimethyl-2,2'-bipyridine) with 4,4'-dimethyl-2,2'-bipyridine (4,4-dmbpy), [Pt(dbbpy)]Cl-2 (dbbpy = 4,4'-dibutyl-2,2'-bipyridine), [Pt(dpbpy)]Cl-2 (dpbpy = 4,4'-dipentyl-2,2'-bipyridine) with 5,5'-dimethyl-2,2'-bipyridine (5,5-dmbpy) affords the following complexes: [(4,4-dmbpy) Pt(5,5-dmbpy)][PF6](2) (1) and [(dbbpy) Pt(5,5-dmbpy)][PF6](2) (2), [(dpbpy) Pt(5,5-dmbpy)][PF6](2) (3), [(5,5-dmbpy) Pt(5,5-dmbpy)][PF6](2) (4). This study was synthesized new platinum complex compounds utilizing ligand of 5,5'-Dimethyl-2,2'-dipyridyl System. To study the chemical composition was used H-1(C-13)-NMR, UV-vis, Spectro photometer and Measurements about optical physics and chemical properties were measured to use spectrofluorometer. UV-vis absorption area was measured 310 nm to 383 nm and luminous wavelength was measured 390 nm to 419 nm.

• 出版日期2014-8