1,7-dithioxo systems. Reaction of bis(5,5-dimethyl-3-thioxocyclohex-1-en-1-yl) sulfide with amines

作者:Timokhina L V*; Sokol'nikova O V; Kanitskaya L V; Yashchenko M P; Voronkov M G
来源:Russian Journal of Organic Chemistry, 2008, 44(4): 532-535.
DOI:10.1134/S1070428008040118

摘要

Reactions of amines (N,N-dimethylethane-1,2-diamine, benzylamine, aniline) with bis(5,5-dimethyl-3-thioxocyclohex-1-en-1-yl) sulfide result in cleavage of the sulfide bond and formation of the corresponding 3-amino-5,5-dimethylcyclohex-2-ene-1-thiones. Aminolysis of bis(5,5-dimethyl-3-oxocyclohex-1-en-1-yl) sulfide occurs at the carbonyl groups with conservation of the divinyl sulfide fragment.

  • 出版日期2008-4