Nanostructured rhodium: electrochemical behaviour and electrodeposition from low-temperature carbamide- and acetamide-containing melts

作者：Kochetova S; Savchuk A; Malyshev V; Gon Eskar M; Solianyk L^*

来源：Materialwissenschaft und Werkstofftechnik, 2015, 46(10): 1046-1049.

DOI：10.1002/mawe.201500400

• Rhodium
• carbamide
• acetamide
• synthesis of nanoparticles
• nanocoating
• nanostructure
• cathodic reduction

It was ascertained that in carbamide- and acetamide-chloride melts at anodic dissolution of rhodium some mixed complexes [Rh(NH3)(4)Cl-2](+) form which are of quasi-octahedral structure and D4h symmetry. During cathodic reduction of the obtained complexes Rh(III) in the investigated melts the synthesis of nanoparticles Rh was carried out as well as nanocoating of Fe, Cu and Mo by them.

• 出版日期2015-10