An Efficient Catalyst System for Pd-Catalyzed Amination of [2.2]Paracyclophanyl Bromides

作者:Qu Bo; Ma Yudao*; Ma Qingshuang; Liu Xiao; He Fuyan; Song Chun
来源:Journal of Organic Chemistry, 2009, 74(17): 6867-6869.
DOI:10.1021/jo901310a

摘要

A practical Buchwald-Hartwig amination of [2.2]paracyclophanyl bromides with benzhydrylideneamine is developed. The method provides a Facile route to a variety of imino and amino [2.2]paracyclophanes that are otherwise not readily synthesized.