Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)(2)] (M = Rh, Ir; X = Cl, I) complexes

作者：Savka R; Plenio H^*

来源：Dalton Transactions, 2015, 44(3): 891-893.

DOI：10.1039/c4dt03449j

The reactions of [MCl(cod)](2) (M = Rh, Ir) with different NHC center dot HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)(2)] (M = Rh, Ir) is also reported.

• 出版日期2015