Non-traditional Ziegler-Natta catalysis in alpha-olefin transformations: reaction mechanisms and product design

作者：Nifant%apos; ev Ilya; Ivchenko Pavel; Tavtorkin Alexander; Vinogradov Alexey; Vinogradov Alexander

来源：Pure and Applied Chemistry, 2017, 89(8): 1017-1032.

DOI：10.1515/pac-2016-1131

<jats:title>Abstract</jats:title><jats:p>This paper describes our recent results in the field of zirconocene-catalyzed α-oltfin transformations, and focuses on questions regarding the reaction mechanism, rational design of zirconocene pre-catalysts, as well as prospective uses of α-olefin products. It has been determined that a wide range of α-olefin-based products, namely vinylidene dimers, oligomers and polymers, can be prepared</jats:p>

• 出版日期2017-8