Nephelauxetic effect in high-pressure luminescence of transition-metal ion dopants

作者:Suchocki A*; Biernacki S W; Grinberg M
来源:Journal of Luminescence, 2007, 125(1-2): 266-270.
DOI:10.1016/j.jlumin.2006.08.039

摘要

Application of the model of the nephelauxetic effect based on Harrison theory of bonding to various transition-metal dopants is reviewed. This one-parameter model describes pressure dependence of the nephelauxetic effect in various compounds with a very good accuracy. Additional studies are necessary to reveal the dependence of fitting parameter on the properties of more complicated many-element compounds.

  • 出版日期2007-8