A synthesis of a 1,1 %26apos;-desymmetrised ferrocene backbone and its facile one-pot double-%26quot;click%26quot; functionalisation

作者:Ilyashenko Gennadiy*; Al Safadi Rawan; Donnan Robert; Dubrovka Rostyslav; Pancholi Jessica; Watkinson Michael; Whiting Andrew
来源:RSC Advances, 2013, 3(38): 17081-17087.
DOI:10.1039/c3ra43054e

摘要

A one-pot, four-component, copper-catalysed double-%26quot;click%26quot; functionalisation of a novel 1,1%26apos;-desymmetrised ferrocene backbone is reported. Using an array of alkynes and azides, a library of ferrocene compounds was developed, demonstrating the scope of this methodology for its potential application in the assembly of novel materials, ligands or biological sensors.

  • 出版日期2013