Aminooxycarbene behavior of a carbamoylsilane

作者：Cunico RF^*

来源：Tetrahedron Letters, 2001, 42(16): 2931-2932.

DOI：10.1016/S0040-4039(01)00336-7

• carbamoylsilane
• siloxyaminocarbene
• carbamoylsilylation

A carbamoylsilane behaves as a siloxyaminocarbene towards electrophilic reagents, undergoing C-H insertion with chloroform, methyl propiolate and 1-chloro-2,4-dinitrobenzene. Its reaction with DMAD results in carbamoylsilylation.

• 出版日期2001-4-16