Indium(III) catalysed substrate selective hydrothiolation of terminal alkynes

作者：Sarma Rupam; Rajesh Nimmakuri; Prajapati Dipak^*

来源：Chemical communications, 2012, 48(33): 4014-4016.

DOI：10.1039/c2cc30350g

In(OTf)(3) is reported as the first catalyst having the ability to selectively catalyse both Markovnikov and anti-Markovnikov hydrothiolation of terminal alkynes under identical reaction conditions depending upon the nature of the thiol employed.

• 出版日期2012