A thermo-responsive structural switch and colossal anisotropic thermal expansion in a chiral organic solid

作者:Janiak Agnieszka; Esterhuysen Catharine; Barbour Leonard J
来源:Chemical Communications, 2018, 54(30): 3727-3730.
DOI:10.1039/c8cc00952j

摘要

The apohost form of a chiral trianglimine compound exists in at least three polymorphic forms. Despite similar packing arrangements, only two of these forms exhibit anomalous thermal expansion behaviour, and undergo thermally-induced interconversion.

  • 出版日期2018-4-15