A novel route for electrosynthesis of CuCr2O4 nanocomposite with p -type conductive polymer as a high performance material for electrochemical supercapacitors

作者：Shayeh Javad Shabani; Sadeghinia Mohammad; Siadat Seyed Omid Ranaei; Ehsani Ali; Rezaei Mehran; Omidi Meisam

来源：Journal of Colloid and Interface Science, 2017, 496: 401-406.

DOI：10.1016/j.jcis.2017.02.010

• Poly pyrrole
• CuCr2O4 NPs
• Supercapacitors
• Electropolymerization
• Nanocomposite

In this work, supercapacitive performance of polypyrrole copper chromate nano particles (Ppy/CuCr(2)O(4)NPs) was studied. CuCr2O4 NPs with the average size of 20 nm were synthesized simply by hydrothermal method and the composite electrodes were then electropolymerized on the surface of glassy carbon electrode. Common surface analysis techniques such as scanning electron microscopy (SEM), transmission electron microscopy(TEM) and Fourier transform infrared (FTIR) were used to study the morphology and structure of the composite. Furthermore, for electrochemical evaluation of composite electrodes, techniques including cyclic voltammetry (CV), galvanostatic charge discharge (CD) and impedance spectroscopy (EIS) were used. Using cyclic voltammetry, the specific capacitance values of Ppy and Ppy/CuCr2O4 NPs were calculated to be 109 and 508 F g(-1), respectively. Results show that using CuCr(2)O(4)NPs in the structure of polymeric films led to increased specific capacitance of composite electrodes more than four times that of poly pyrrole. Increasing the conductivity and stability of composite electrodes through continuous cycles are the other advantages of using CuCr2O4 NPs as active materials in a polymeric structure.

• 出版日期2017-6-15